Product ID:84-0546, ETHYL ACETATE:PETROLEUM ETHER 1:2 SOLUTION
MSDS Date:09/05/2000
FSC:NIIN:Submitter:D DG
Status Code:A
Kit Part:Y
MSDS Number: CLFTT

CAROLINA BIOLOGICAL SUPPLY CO

2700 YORK RD
BURLINGTON, NC 27215-3387
US

Emergency Phone: 800-424-9300

Info Phone: 800-227-1150/910-584-0381

Cage: 59896

CAROLINA BIOLOGICAL SUPPLY CO

BURLINGTON, NC 27215-3387 US

Telephone: 800-227-1150/910-584-0381

Cage: 59896

PETROLEUM ETHER

CAS: 8032-32-4

RTECS: OI6180000

OSHA PEL 300 PPM

ACGIH TLV: 300 PPM

ETHYL ACETATE

CAS: 141-78-6

RTECS: AH5425000

OSHA PEL 400 PPM/1400 MG/M3

ACGIH TLV: 1440 MG/M3;400 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

LD50 LC50 Mixture:N/P[
Routes of Entry: Inhalation:YES Skin:UNKNOWN Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:TARGET ORGANS: LUNGS, CENTRAL NERVOUS
SYSTEM, EYES, SKIN, MUCOUS SURFACES. EYES: MAY CAUSE IRRITATION.
SKIN: MAY CAUSE IRRITATION. INGESTION: MAY CAUSE GASTROINTESTINAL
DISCOMFORT. INHALTION: MAY CAUS E IRRITATION TO RESPIRATORY TRACT.
Explanation of Carcinogenicity:NEITHER COMPONENT IS LISTED AS CAUSING
CANCER BY NTP, IARC, OR OSHA.
Medical Cond Aggravated by Exposure:RESPIRATORY, KIDNEY, LIVER, SKIN
AND BLOOD DISORDERS.

First Aid:EYES-FLUSH WITH WATER FOR 15 MINS, RAISING/LOWERING EYELIDS
OCCASIONALLY. GET MEDICAL ATTENTION IF IRRITATION PERSISTS.
SKIN-THOROUGHLY WASH EXPOSED AREA FOR 15 MINS. REMOVE CONTAMINATED
CLOTHING, LAU NDER BEFORE REUSE. GET MEDICAL ATTENTION.
INGESTION-IF CONSCIOUS, GIVE PLENTY OF WATER & INDUCE VOMITING
IMMEDIATELY AS DIRECTED BY MEDICAL PERSONNEL. IMMEDIATELY CALL
PHYSICIAN OR POISON CONTROL CENT ER. NEVER GIVE ANYTHING BY MOUTH
TO AN UNCONSCIOUS PERSON. INHALTION-REMOVE TO FRESH AIR. GIVE
OXYGEN IF BREATHING IS DIFFICULT; GIVE ARTIFICIAL RESPIRATION IF
BREATHING STOPPED. KEEP PERSON WARM, QUI ET, GET MEDICAL ATTENTION.

Extinguishing Media:USE DRY CHEMICAL, CO2, OR APPROPRIATE FOAM.
Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR FULL PROTECTIVE
EQUIPMENT AND NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS.
Unusual Fire/Explosion Hazard:NONE KNOWN.

Spill Release Procedures:VENTILATE AREA OF SPILL. ELIMINATE ALL SOURCES
OF IGNITION. REMOVE ALL NON-ESSENTIAL PERSONNEL FROM AREA. CLEAN-UP
PERSONNEL SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND CLOTHING.
ABSORB MATERIAL WITH SUITABLE ABSORBENT AND CONTAINERIZE FOR
DISPOSAL.

Handling and Storage Precautions:KEEP CONTAINER TIGHTLY CLOSED. STORE
IN A COOL AREA AWAY FROM SOURCES OF IGNITION AND OXIDIZERS.
RETAINED RESIDUE MAY MAKE CONTAINERS HAZARDOUS
Other Precautions:DO NOT BREATHE VAPORS. DO NOT TAKE INTERNALLY.

Respiratory Protection:A NIOSH/MSHA CHEMICAL CARTRIDGE RESPIRATOR
SHOULD BE WORN IF PEL OR TLV IS EXCEEDED.
Ventilation:LOCAL EXHAUST/MECHANICAL(GENERAL): YES
Protective Gloves:RUBBER, NEOPRENE, PVC, OR EQUIVALENT
Eye Protection:SPLASH PROOF CHEMICAL SAFETY GOGGLES SHOULD BE WORN AT
ALL TIMES.
Other Protective Equipment:LAB COAT, EYE WASH, AND SAFETY SHOWER.
Supplemental Safety and Health
PART OF 5 PART KIT. CONTRACTR`S PART NUMBER/TRADE NAME: CK FUNDAMENTAL
OF CHROMATOGRAPHY/ITEM 84-0546. SEE MSDS SERIAL # CLFTQ, CKZMP,
CLFVG, AND CLFTL.

HCC:F1
Evaporation Rate & Reference:N/A (H20=1)
Appearance and Odor:CLEAR, COLORLESS LIQUID.
Percent Volatiles by Volume:~95%

Stability Indicator/Materials to Avoid:YES
ACIDS, OXIDIZERS, STRONG ALKALIES, NITRATES
Stability Condition to Avoid:HEAT, CONTACT WITH IGNITION SOURCES
Hazardous Decomposition Products:COX

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH ALL APPLICABLE
FEDERAL, STATE AND LOCAL REGULATION. ALWAYS CONTACT A PERMITTED
WASTE DISOSER (TSD) TO ASSURE COMPLIANCE.

Toxicological Information:TOXICITY DATA: PETROLEUM ETHER IHL-RAT LC50:
3400 PPM/4H. ETHYL ACETATE ORL-RAT LD50: 5620 MG/KG; IHL-MUS. LC50:
45 G/CU METER. EFFECTS OF OVEREXPOSURE: MUTAGENIC EFFECTS DATA
CITED FOR ETHYL ACETATE. **EMERGENCY OVERVIEW: FOR PETROLEUM
ETHER: IRRITATING TO SKIN & EYES. MAY CAUSE DIZZINESS, NAUSEA,
RESPIRATORY AND CARDIAC EFFECTS.

Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ecological:EPA WASTE NUMBERS: U112, D001.

Transport Information:UN1993.

SARA Title III Information:HAZARD CATEGORY FOR SARA SECTION 311/312
REPORTING: ACUTE, CHRONIC, FIRE.
Federal Regulatory Information:EPA TSCA STATUS: ON TSCA INVENTORY.
CERCLA SEC. 103 RQ LBS: ETHYL ACETATE-5000.